We have to compare wavelength of transition in the H-spectrum with the Balmer transition n = 4 to n = 2 of He+ spectrum. Since λH = λHe+ ∴ RHZH2[n121−n221] = RHZHe+2[221−421] 1 × [n121−n221] = 4 × (41×161)[n121−n221] = 4 × rac4−116[n121−n221] = rac34 If n1 = 1 , then n2 = 2 , 3 , ... For first line n2 = 2 , n1 = 1 [n121−n221] = 11−41 = rac34 Hence, trnasition n2 = 2 to n1 = 1 will give spectrum of the same wavelength as that of Balmer transition, n2 = 4 to n1 = 2 in He+.