JEE Main 2020 Free Model Papers With Solutions
About Exam
 It is the only platform for engineering aspirants seeking admission in IIITs, NITs, and other centrally funded technical institutes.
 JEE Main is the first step for IIT aspirants to get admission in top IITs and other premier institutes across the country through Advanced.
Joint Entrance Examination (JEE) Main is conducted to offer admissions to interested candidates in undergraduate engineering programmes at NITs (National Institutes of Technology), IIITs (Indian Institutes of Information Technology) and other centrally funded technical institutions (CFTIs) across the country. JEE Main Paper1 is for candidates seeking to pursue BE/BTech at NITs, IIITs, and CFTIs. This exam is also the eligibility test for JEE advanced which is the entrance exam for admissions to programmes offered by the 23 IITs in India. Only the top 2,24,000 score holders in JEE Main exam are eligible to apply for JEE Advanced Exam and PaperII for B.Arch admissions.
States like Odisha, Madhya Pradesh, Haryana, Uttarakhand and Nagaland & some other institutions use JEE Main ranks for admissions; however, admission criteria for the mentioned states will be notified by the concerned state authorities only
The new changes in JEE Main 2019 allow for candidates to appear twice for the entrance exam in a given year. The better of the two scores will be used for the purpose of ranking as per the regulations laid by the authorities. Form 2019, Bihar and Jharkhand have joined the JEE Main system and the state entrance exams have been done away with.
Exam Pattern
JEE Main Paper 1 (B.E or B.Tech Courses)
 Exam Mode: Computerbased offline exam. The students will have to mark their responses on already downloaded answer sheets.
 Exam Duration: 3 hours
 The Questions will be from topics covered in Physics, Chemistry, and Maths.
 Nature of Questions: Single correct Objective type multiple choice questions.
 The paper will have a total of 90 questions (360 marks) with 30 from each Physics, Chemistry, and Maths
JEE Main Paper 1 Marking Scheme
 For every correct answer, 4 marks will be awarded while 1 mark will be deducted for every incorrect answer.
 There is no negative marking for questions left unattempted.
 Only one response has to be filled in, more than one response will be judged as a wrong answer and will result in negative marking.
JEE Main Paper 2 (B.Arch or B.Plan Courses)
 Exam Mode: Offline Exam
 Exam Duration: 3 hours
 The Questions will be from topics covered in Maths, General Aptitude, and Drawing Skills.
 Mathematics and Aptitude will have single correct objective type multiple choice questions. Drawing test will evaluate the sketching and drawing skills.
 The Aptitude Test consists of 50 questions (200 marks). Maths section consists of 30 questions (120 marks) and the Drawing test comprises of 2 questions (70 marks).
JEE Main Paper 2 Marking Scheme
 For every correct answer in Maths and Aptitude section, 4 marks will be awarded while 1 mark will be deducted for every incorrect answer.
 There is no negative marking for Drawing questions.
Eligibility
JEE Main 2019 Eligibility Criteria
The eligibility criteria describe all the terms and conditions that a JEE Main aspirant has to satisfy for being eligible. Hence, to avoid rejections in later stages, the students are advised to know the eligibility criteria before registering for the exam.
 Age Criteria: There is no age limit prescribed by NTA for appearing in JEE Main 2019 January and April exams.
 Qualifying Exam: Irrespective of their age the applicant must qualify i.e. 2019 appearing students or have qualified their class 12th or any equivalent exam in 2017 or 2018.
 Qualifying Marks: There is no minimum pass percentage for appearing in JEE Main exam. However, the applicants must pass their class 12 board or other equivalent examination.
 Criteria For admissions in NITs, IIITs, and GFTIs: The candidate must secure 75% Marks in their class 12 board exams or should be within the top 20 percentile of their respective boards. For reserved category candidates, the minimum percentage required for admissions in NITs, IIITs, and GFTIs is 65%.
Eligibility Criteria for JEE Main Paper 2
 The Diploma holders are not eligible for this exam.
 The candidate must have secured 50% marks in Maths, Physics, and Chemistry along with 50% aggregate marks in the qualifying examination.
 Mathematics is compulsory for candidates applying for B.Arch./B.Planning courses.
JEE Main Mathematics Syllabus
Units 
Topics 

UNIT 1: Sets, relations and functions  Sets and their representation; Union, intersection and complement of sets and their algebraic properties; Power set; Relation, Types of relations, equivalence relations, functions; Oneone, into and onto functions, composition of functions. 
UNIT 2: Complex numbers and quadratic equations 
Complex numbers as ordered pairs of reals, Representation of complex numbers in the form a+ib and their representation in a plane, Argand diagram, algebra of complex numbers, modulus and argument (or amplitude) of a complex number, square root of a complex number, triangle inequality, Quadratic equations in real and complex number system and their solutions. Relation between roots and coefficients, nature of roots, formation of quadratic equations with given roots. 
UNIT 3: Matrices and determinants  Matrices, algebra of matrices, types of matrices, determinants and matrices of order two and three. Properties of determinants, evaluation of determinants, area of triangles using determinants. Adjoint and evaluation of inverse of a square matrix using determinants and elementary transformations, Test of consistency and solution of simultaneous linear equations in two or three variables using determinants and matrices. 
UNIT 4: Permutations and combinations 
Fundamental principle of counting, permutation as an arrangement and combination as selection, Meaning of P (n,r) and C (n,r), simple applications. 
UNIT 5: Mathematical induction 
Principle of Mathematical Induction and its simple applications 
UNIT 6: Binomial theorem and its simple applications 
Binomial theorem for a positive integral index, general term and middle term, properties of Binomial coefficients and simple applications. 
UNIT 7: Sequences and series 
Arithmetic and Geometric progressions, insertion of arithmetic, geometric means between two given numbers. Relation between A.M. and G.M. Sum upto n terms of 
UNIT 8: Limit, continuity and differentiability 
Real – valued functions, algebra of functions, polynomials, rational, trigonometric, logarithmic and exponential functions, inverse functions. Graphs of simple functions. Limits, continuity and differentiability. Differentiation of the sum, difference, product and quotient of two functions. Differentiation of trigonometric, inverse trigonometric, logarithmic, exponential, composite and implicit functions; derivatives of order upto two. Rolle’s and Lagrange’s Mean Value Theorems. Applications of derivatives: Rate of change of quantities, monotonic – increasing and decreasing functions, Maxima and minima of functions of one variable, tangents and normals 
UNIT 9: Integral calculus 
Integral as an anti – derivative. Fundamental integrals involving algebraic, trigonometric, exponential and logarithmic functions. Integration by substitution, by parts and by partial fractions. Integration using trigonometric identities. 
Evaluation of simple integrals of the type Integral as limit of a sum. Fundamental Theorem of Calculus. Properties of definite integrals. Evaluation of definite integrals, determining areas of the regions bounded by simple curves in standard form. 

UNIT 10: Differential equations 
Ordinary differential equations, their order and degree. Formation of differential equations. Solution of differential equations by the method of separation of variables, solution of homogeneous and linear differential equations of the type: dy/dx+p(x)y=q(x) 
UNIT 11: Coordinate geometry 
Cartesian system of rectangular coordinates 10 in a plane, distance formula, section formula, locus and its equation, translation of axes, slope of a line, parallel and perpendicular lines, intercepts of a line on the coordinate axes. 
Straight lines: Various forms of equations of a line, intersection of lines, angles between two lines, conditions for concurrence of three lines, distance of a point from a line, equations of internal and external bisectors of angles between two lines, coordinates of centroid, orthocentre and circumcentre of a triangle, equation of family of lines passing through the point of intersection of two lines. 

Circles, conic sections: Standard form of equation of a circle, general form of the equation of a circle, its radius and centre, equation of a circle when the end points of a diameter are given, points of intersection of a line and a circle with the centre at the origin and condition for a line to be tangent to a circle, equation of the tangent. Sections of cones, equations of conic sections (parabola, ellipse and hyperbola) in standard forms, condition for y = mx + c to be a tangent and point (s) of tangency. 

UNIT 12: Three dimensional geometry 
Coordinates of a point in space, distance between two points, section formula, direction ratios and direction cosines, angle between two intersecting lines. Skew lines, the shortest distance between them and its equation. Equations of a line and a plane in different forms, intersection of a line and a plane, coplanar lines. 
UNIT 13: Vector algebra 
Vectors and scalars, addition of vectors, components of a vector in two dimensions and three dimensional space, scalar and vector products, scalar and vector triple product. 
UNIT 14: Statistics and probability 
Measures of Dispersion: Calculation of mean, median, mode of grouped and ungrouped data calculation of standard deviation, variance and mean deviation for grouped and ungrouped data.

UNIT 15: Trigonometry 
Trigonometrical identities and equations. Trigonometrical functions. Inverse trigonometrical functions and their properties. Heights and Distances. 
UNIT 16: Mathematical reasoning 
Statements, logical operations and, or, implies, implied by, if and only if. Understanding of tautology, contradiction, converse and contrapositive. 
JEE Main Physics Syllabus
Units 
Topics 

Unit 1: Physics And Measurement 
Physics, technology and society, S I units, Fundamental and derived units. Least count, accuracy and precision of measuring instruments, Errors in measurement, Dimensions of Physical quantities, dimensional analysis and its applications 
Unit 2: Kinematics 
Frame of reference. Motion in a straight line: Positiontime graph, speed and velocity. Uniform and nonuniform motion, average speed and instantaneous velocity Uniformly accelerated motion, velocitytime, positiontime graphs, relations for uniformly accelerated motion. Scalars and Vectors, Vector addition and Subtraction, Zero Vector, Scalar and Vector products, Unit Vector, Resolution of a Vector. Relative Velocity, Motion in a plane, Projectile Motion, Uniform Circular Motion 
Unit 3: Laws Of Motion 
Force and Inertia, Newton’s First Law of motion; Momentum, Newton’s Second Law of motion; Impulse; Newton’s Third Law of motion. Law of conservation of linear momentum and its applications, Equilibrium of concurrent forces. 
Static and Kinetic friction, laws of friction, rolling friction 

Dynamics of uniform circular motion: Centripetal force and its applications. 

Unit 4: Work,Energy And Power 
Work done by a constant force and a variable force; kinetic and potential energies, work energy theorem, power. 
Potential energy of a spring, conservation of mechanical energy, conservative and nonconservative forces; Elastic and inelastic collisions in one and two dimensions. 

Unit 5: Rotational Motion 
Centre of mass of a twoparticle system, Centre of mass of a rigid body; Basic concepts of rotational motion; moment of a force, torque, angular momentum, conservation of angular momentum and its applications; moment of inertia, radius of gyration. Values of moments of inertia for simple geometrical objects, parallel and perpendicular axes theorems and their applications. Rigid body rotation, equations of rotational motion. 
Unit 6: Gravitation 
The universal law of gravitation. Acceleration due to gravity and its variation with altitude and depth. Kepler’s laws of planetary motion. Gravitational potential energy; gravitational potential. Escape velocity. Orbital velocity of a satellite. Geostationary satellites. 
Unit 7: Properties Of Solids And Liquids 
Elastic behaviour, Stressstrain relationship, Hooke’s Law, Young’s modulus, bulk modulus, modulus of rigidity. Pressure due to a fluid column; Pascal’s law and its applications. Viscosity, Stokes’ law, terminal velocity, streamline and turbulent flow, Reynolds number. Bernoulli’s principle and its applications. Surface energy and surface tension, angle of contact, application of surface tension – drops, bubbles and capillary rise. Heat, temperature, thermal expansion; specific heat capacity, calorimetry; change of state, latent heat. Heat transferconduction, convection and radiation, Newton’s law of cooling. 
Unit 8: Thermodynamics 
Thermal equilibrium, zeroth law of thermodynamics, concept of temperature. Heat, work and internal energy. First law of thermodynamics. Second law of thermodynamics: reversible and irreversible processes. Carnot engine and its efficiency. 
Unit 9: Kinetic Theory Of Gases 
Equation of state of a perfect gas, work done on compressing a gas. Kinetic theory of gases – assumptions, concept of pressure. Kinetic energy and temperature: rms speed of gas molecules; Degrees of freedom, Law of equipartition of energy, applications to specific heat capacities of gases; Mean free path, Avogadro’s number. 
Unit 10: Oscillations And Waves 
Periodic motion – period, frequency, displacement as a function of time. Periodic functions. Simple harmonic motion (S.H.M.) and its equation; phase; oscillations of a spring restoring force and force constant; energy in S.H.M. – kinetic and potential energies; Simple pendulum – derivation of expression for its time period; Free, forced and damped oscillations, resonance 
Wave motion. Longitudinal and transverse waves, speed of a wave. Displacement relation for a progressive wave. Principle of superposition of waves, reflection of waves, Standing waves in strings and organ pipes, fundamental mode and harmonics, Beats, Doppler effect in sound 

Unit 11: Electrostatics 
Electric charges: Conservation of charge, Coulomb’s lawforces between two point charges, forces between multiple charges; superposition principle and continuous charge distribution. 

Electric field: Electric field due to a point charge, Electric field lines, Electric dipole, Electric field due to a dipole, Torque on a dipole in a uniform electric field. Electric flux, Gauss’s law and its applications to find field due to infinitely long uniformly charged straight wire, uniformly charged infinite plane sheet and uniformly charged thin spherical shell. Electric potential and its calculation for a point charge, electric dipole and system of charges; Equipotential surfaces, Electrical potential energy of a system of two point charges in an electrostatic field. Conductors and insulators, Dielectrics and electric polarization, capacitor, combination of capacitors in series and in parallel, capacitance of a parallel plate capacitor with and without dielectric medium between the plates, Energy stored in a capacitor.

Unit 12: Currrent Electricity

Electric current, Drift velocity, Ohm’s law, Electrical resistance, Resistances of different materials, VI characteristics of Ohmic and nonohmic conductors, Electrical energy and power, Electrical resistivity, Colour code for resistors; Series and parallel combinations of resistors; Temperature dependence of resistance. Electric Cell and its Internal resistance, potential difference and emf of a cell, combination of cells in series and in parallel. Kirchhoff’s laws and their applications. Wheatstone bridge, Metre bridge. Potentiometer – principle and its applications. 
Unit 13: Magnetic Effects Of Current And Magnetism 
Biot – Savart law and its application to current carrying circular loop. Ampere’s law and its applications to infinitely long current carrying straight wire and solenoid. Force on a moving charge in uniform magnetic and electric fields. Cyclotron. Force on a currentcarrying conductor in a uniform magnetic field. Force between two parallel currentcarrying conductorsdefinition of ampere. Torque experienced by a current loop in uniform magnetic field; Moving coil galvanometer, its current sensitivity and conversion to ammeter and voltmeter. Current loop as a magnetic dipole and its magnetic dipole moment. Bar magnet as an equivalent solenoid, magnetic field lines; Earth’s magnetic field and magnetic elements. Para, dia and ferro magnetic substances. Magnetic susceptibility and permeability, Hysteresis, Electromagnets and permanent magnets. 
Unit 14: Electromagnetic Induction And Alternating Currents 
Electromagnetic induction; Faraday’s law, induced emf and current; Lenz’s Law, Eddy currents. Self and mutual inductance. Alternating currents, peak and rms value of alternating current/ voltage; reactance and impedance; LCR series circuit, resonance; Quality factor, power in AC circuits, wattless current. AC generator and transformer. 
Unit 15: Electromagnetic Waves 
Electromagnetic waves and their characteristics. Transverse nature of electromagnetic waves. Electromagnetic spectrum (radio waves, microwaves, infrared, visible, ultraviolet, Xrays, gamma rays). Applications of e.m. waves.

Unit 16: Optics 
Reflection and refraction of light at plane and spherical surfaces, mirror formula, Total internal reflection and its applications, Deviation and Dispersion of light by a prism, Lens Formula, Magnification, Power of a Lens, Combination of thin lenses in contact, Microscope and Astronomical Telescope (reflecting and refracting) and their magnifying powers. Wave optics: wavefront and Huygens’ principle, Laws of reflection and refraction using Huygen’s principle. Interference, Young’s double slit experiment and expression for fringe width. Diffraction due to a single slit, width of central maximum. Resolving power of microscopes and astronomical telescopes, Polarisation, plane polarized light; Brewster’s law, uses of plane polarized light and Polaroids. 
Unit 17: Dual Nature Of Matter Andradiation 
Dual nature of radiation. Photoelectric effect, Hertz and Lenard’s observations; Einstein’s photoelectric equation; particle nature of light. Matter waveswave nature of particle, de Broglie relation. DavissonGermer experiment. 
Unit 18: Atoms And Nuclei 
Alphaparticle scattering experiment; Rutherford’s model of atom; Bohr model, energy levels, hydrogen spectrum. Composition and size of nucleus, atomic masses, isotopes, isobars; isotones. Radioactivityalpha, beta and gamma particles/rays and their properties; radioactive decay law. Massenergy relation, mass defect; binding energy per nucleon and its variation with mass number, nuclear fission and fusion. 
Unit 19: Electronic Devices 
Semiconductors; semiconductor diode: IV characteristics in forward and reverse bias; diode as a rectifier; IV characteristics of LED, photodiode, solar cell and Zener diode; Zener diode as a voltage regulator. Junction transistor, transistor action, characteristics of a transistor; transistor as an amplifier (common emitter configuration) and oscillator. Logic gates (OR, AND, NOT, NAND and NOR). Transistor as a switch. 
Unit 20: Communication Systems

Propagation of electromagnetic waves in the atmosphere; Sky and space wave propagation, Need for modulation, Amplitude and Frequency Modulation, Bandwidth of signals, Bandwidth of Transmission medium, Basic Elements of a Communication System (Block Diagram only). 
JEE Main Chemistry Syllabus
Units 
Topics 

Section A: Physical Chemistry 

Unit 1: Some Basic Concepts In Chemistry 
Matter and its nature, Dalton’s atomic theory; Concept of atom, molecule, element and compound; Physical quantities and their measurements in Chemistry, precision and accuracy, significant figures, S.I. Units, dimensional analysis; Laws of chemical combination; Atomic and molecular masses, mole concept, molar mass, percentage composition, empirical and molecular formulae; Chemical equations and stoichiometry. 
Unit 2: States Of Matter 
Classification of matter into solid, liquid and gaseous states. 
Gaseous State: Measurable properties of gases; Gas laws – Boyle’s law, Charle’s law, Graham’s law of diffusion, Avogadro’s law, Dalton’s law of partial pressure; Concept of Absolute scale of temperature; Ideal gas equation; Kinetic theory of gases (only postulates); Concept of average, root mean square and most probable velocities; Real gases, deviation from Ideal behaviour, compressibility factor and van der Waals equation. 

Liquid State: Properties of liquids – vapour pressure, viscosity and surface tension and effect of temperature on them (qualitative treatment only). 

Solid State: Classification of solids: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea); Bragg’s Law and its applications; Unit cell and lattices, packing in solids (fcc, bcc and hcp lattices), voids, calculations involving unit cell parameters, imperfection in solids; Electrical, magnetic and dielectric properties. 

Unit 3: Atomic Structure 
Thomson and Rutherford atomic models and their limitations; Nature of electromagnetic radiation, photoelectric effect; Spectrum of hydrogen atom, Bohr model of hydrogen atom – its postulates, derivation of the relations for energy of the electron and radii of the different orbits, limitations of Bohr’s model; Dual nature of matter, deBroglie’s relationship, Heisenberg uncertainty principle. 
Elementary ideas of quantum mechanics, quantum mechanical model of atom, its important features, concept of atomic orbitals as one electron wave functions; various quantum numbers (principal, angular momentum and magnetic quantum numbers) and their significance; shapes of s, p and d – orbitals, electron spin and spin quantum number; Rules for filling electrons in orbitals – aufbau principle, Pauli’s exclusion principle and Hund’s rule, electronic configuration of elements, extra stability of halffilled and completely filled orbitals. 

Unit 4: Chemical Bonding And Molecular Strucure

Kossel – Lewis approach to chemical bond formation, concept of ionic and covalent bonds. 

Ionic Bonding: Formation of ionic bonds, factors affecting the formation of ionic bonds; calculation of lattice enthalpy. 

Covalent Bonding: Concept of electronegativity, Fajan’s rule, dipole moment; Valence Shell Electron Pair Repulsion (VSEPR) theory and shapes of simple molecules. Quantum mechanical approach to covalent bonding: Valence bond theory – Its
important features, concept of hybridization involving s, p and d orbitals; Resonance.

Unit 5: Chemical Thermodynamics 
Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes. 
First law of thermodynamics – Concept of work, heat internal energy and enthalpy, heat capacity, molar heat capacity; Hess’s law of constant heat summation; Enthalpies of bond dissociation, combustion, formation, atomization, sublimation, phase transition, hydration, ionization and solution. Second law of thermodynamics; Spontaneity of processes; DS of the universe and DG of the system as criteria for spontaneity, Dgo (Standard Gibbs energy change) and equilibrium constant. 

Unit 6: Solutions 
Different methods for expressing concentration of solution – molality, molarity, mole fraction, percentage (by volume and mass both), vapour pressure of solutions and Raoult’s Law – Ideal and nonideal solutions, vapour pressure – composition, plots for ideal and nonideal solutions; Colligative properties of dilute solutions – relative lowering of vapour pressure, depression of freezing point, elevation of boiling point and osmotic pressure; Determination of molecular mass using colligative properties; Abnormal value of molar mass, van’t Hoff factor and its significance. 
Unit 7: Equilibrium 
Meaning of equilibrium, concept of dynamic equilibrium. 

Equilibria involving physical processes: Solid liquid, liquid – gas and solid – gas equilibria, Henry’s law, general characterics of equilibrium involving physical processes.


Ionic equilibrium: Weak and strong electrolytes, ionization of electrolytes, various concepts of acids and bases (Arrhenius, Bronsted – Lowry and Lewis) and their ionization, acid – base equilibria (including multistage ionization) and ionization constants, ionization of water, pH scale, common ion effect, hydrolysis of salts and pH of their solutions, solubility of sparingly soluble salts and solubility products, buffer solutions. 
Unit 8: Redox Reactions And Electrochemistry 
Electronic concepts of oxidation and reduction, redox reactions, oxidation number, rules for assigning oxidation number, balancing of redox reactions. 
Eectrolytic and metallic conduction, conductance in electrolytic solutions, specific and molar conductivities and their variation with concentration: Kohlrausch’s law and its applications. 

Electrochemical cells – Electrolytic and Galvanic cells, different types of electrodes, electrode potentials including standard electrode potential, half – cell and cell reactions, emf of a Galvanic cell and its measurement; Nernst equation and its applications; Relationship between cell potential and Gibbs’ energy change; Dry cell and lead accumulator; Fuel cells. 

Unit 9 : Chemical Kinetics 
Rate of a chemical reaction, factors affecting the rate of reactions: concentration, temperature, pressure and catalyst; elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units, differential and integral forms of zero and first order reactions, their characteristics and half – lives, effect of temperature on rate of reactions – Arrhenius theory, activation energy and its calculation, collision theory of bimolecular gaseous reactions (no derivation). 
Unit10 : Surface Chemistry 
Adsorption Physisorption and chemisorption and their characteristics, factors affecting adsorption of gases on solids – Freundlich and Langmuir adsorption isotherms, adsorption from solutions. 
Colloidal state distinction among true solutions, colloids and suspensions, classification of colloids – lyophilic, lyophobic; multi molecular, macromolecular and associated colloids (micelles), preparation and properties of colloids – Tyndall effect, Brownian movement, electrophoresis, dialysis, coagulation and flocculation; Emulsions and their characteristics. 

Section B: Inorganic Chemistry 

Unit 11: Classificaton Of Elements And Periodicity In Properties 
Modem periodic law and present form of the periodic table, s, p, d and f block elements, periodic trends in properties of elements atomic and ionic radii, ionization enthalpy, electron gain enthalpy, valence, oxidation states and chemical reactivity. 
Unit 12: General Principles And Processes Of Isolation Of Metals 
Modes of occurrence of elements in nature, minerals, ores; Steps involved in the extraction of metals – concentration, reduction (chemical and electrolytic methods) and refining with special reference to the extraction of Al, Cu, Zn and Fe; Thermodynamic and electrochemical principles involved in the extraction of metals. 
Unit 13: Hydrogen 
Position of hydrogen in periodic table, isotopes, preparation, properties and uses of hydrogen; Physical and chemical properties of water and heavy water; Structure, preparation, reactions and uses of hydrogen peroxide; Hydrogen as a fuel. 
Unit 14: S – Block Elements (Alkali And Alkaline Earth Metals) 
Group – 1 and 2 Elements: General introduction, electronic configuration and general trends in physical and chemical properties of elements, anomalous properties of the first element of each group, diagonal relationships. 

Preparation and properties of some important compounds – sodium carbonate and sodium hydroxide; Industrial uses of lime, limestone, Plaster of Paris and cement; Biological significance of Na, K, Mg and Ca. 
Unit 15: P – Block Elements 
Group – 13 to Group 18 Elements: General Introduction: Electronic configuration and general trends in physical and chemical properties of elements across the periods and down the groups; unique behaviour of the first element in each group. 

Groupwise study of the p – block elements Group – 13: Preparation, properties and uses of boron and aluminium; properties of boric acid, diborane, boron trifluoride, aluminium chloride and alums. Group – 14: Allotropes of carbon, tendency for catenation; Structure & properties of silicates, and zeolites. Group – 15: Properties and uses of nitrogen and phosphorus; Allotrophic forms of phosphorus; Preparation, properties, structure and uses of ammonia, nitric acid, phosphine and phosphorus halides, (PCl3, PCl5); Structures of oxides and oxoacids of phosphorus. Group – 16: Preparation, properties, structures and uses of ozone; Allotropic forms of sulphur; Preparation, properties, structures and uses of sulphuric acid (including its industrial preparation); Structures of oxoacids of sulphur. Group – 17: Preparation, properties and uses of hydrochloric acid; Trends in the acidic nature of hydrogen halides; Structures of Interhalogen compounds and oxides and oxoacids of halogens. Group –18: Occurrence and uses of noble gases; Structures of fluorides and oxides of xenon. 
UNIT 16: D – And F – BLOCK ELEMENTS 
Transition Elements: General introduction, electronic configuration, occurrence and characteristics, general trends in properties of the first row transition elements – physical properties, ionization enthalpy, oxidation states, atomic radii, colour, catalytic behaviour, magnetic properties, complex formation, interstitial compounds, alloy formation; Preparation, properties and uses of K2 Cr2 O7 and KMnO4 . 
Inner Transition Elements: Lanthanoids – Electronic configuration, oxidation states and lanthanoid contraction. 

Actinoids – Electronic configuration and oxidation states. 

Unit 17: CoOrdination Compounds 
Introduction to coordination compounds, Werner’s theory; ligands, coordination number, denticity, chelation; IUPAC nomenclature of mononuclear coordination compounds, isomerism; BondingValence bond approach and basic ideas of Crystal field theory, colour and magnetic properties; Importance of coordination compounds (in qualitative analysis, extraction of metals and in biological systems). 
Unit 18: Environmental Chemistry 
Environmental pollution – Atmospheric, water and soil. Atmospheric pollution – Tropospheric and Stratospheric Tropospheric pollutants – Gaseous pollutants: Oxides of carbon, nitrogen and sulphur, hydrocarbons; their sources, harmful effects and prevention; Greenhouse effect and Global warming; Acid rain; Particulate pollutants: Smoke, dust, smog, fumes, mist; their sources, harmful effects and prevention. Stratospheric pollution Formation and breakdown of ozone, depletion of ozone layer – its mechanism and effects. Water Pollution – Major pollutants such as, pathogens, organic wastes and chemical pollutants; their harmful effects and prevention. Soil pollution – Major pollutants such as: Pesticides (insecticides,. herbicides and fungicides), their harmful effects and prevention. Strategies to control environmental pollution.

Section C: Organic Chemistry 

Unit 19: Purification And Characterisation Of Organic Compounds 
Purification – Crystallization, sublimation, distillation, differential extraction and chromatography – principles and their applications 
Qualitative analysis – Detection of nitrogen, sulphur, phosphorus and halogens. 

Quantitative analysis (basic principles only) – Estimation of carbon, hydrogen, nitrogen, halogens, sulphur, phosphorus. 

Calculations of empirical formulae and molecular formulae; Numerical problems in organic quantitative analysis. 

Unit 20: Some Basic Principles Of Organic Chemistry 
Tetravalency of carbon; Shapes of simple molecules – hybridization (s and p); Classification of organic compounds based on functional groups: – C = C – , – C h C – and those containing halogens, oxygen, nitrogen and sulphur; Homologous series; Isomerism – structural and stereoisomerism. 

Nomenclature (Trivial and IUPAC)

Unit 21: Hydrocarbons 
Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties and reactions.

Alkenes – Geometrical isomerism; Mechanism of electrophilic addition: addition of hydrogen, halogens, water, hydrogen halides (Markownikoff’s and peroxide effect); Ozonolysis and polymerization. 

Alkynes – Acidic character; Addition of hydrogen, halogens, water and hydrogen halides; Polymerization. 

Aromatic hydrocarbons – Nomenclature, benzene – structure and aromaticity; Mechanism of electrophilic substitution: halogenation, nitration, Friedel – Craft’s alkylation and acylation, directive influence of functional group in monosubstituted benzene. 

Unit 22: Organic Compounds Containing Halogens 
General methods of preparation, properties and reactions; Nature of CX bond; Mechanisms of substitution reactions. 
Uses; Environmental effects of chloroform & iodoform. 

Unit 23: Organic Compounds Containing Oxygen 
General methods of preparation, properties, reactions and uses. 
Alcohols, Phenols And Ethers 
Alcohols: Identification of primary, secondary and tertiary alcohols; mechanism of dehydration. Phenols: Acidic nature, electrophilic substitution reactions: halogenation, nitration and sulphonation, Reimer – Tiemann reaction. Ethers: Structure. Aldehyde and Ketones: Nature of carbonyl group;Nucleophilic addition to >C=O group, relative reactivities of aldehydes and ketones; Important reactions such as – Nucleophilic addition reactions (addition of HCN, NH3 and its derivatives), Grignard reagent; oxidation; reduction (Wolff Kishner and Clemmensen); acidity of r – hydrogen, aldol condensation, Cannizzaro reaction, Haloform reaction; Chemical tests to distinguish between aldehydes and Ketones. 
Carboxylic Acids 
Acidic strength and factors affecting it.

UNIT 24: ORGANIC COMPOUNDS CONTAINING NITROGEN 
General methods of preparation, properties, reactions and uses. Amines: Nomenclature, classification, structure, basic character and identification of primary, secondary and tertiary amines and their basic character. Diazonium Salts: Importance in synthetic organic chemistry. 
UNIT 25: POLYMERS 
General introduction and classification of polymers, general methods of polymerizationaddition and condensation, copolymerization; Natural and synthetic rubber and vulcanization; some important polymers with emphasis on their monomers and uses – polythene, nylon, polyester and bakelite. 
UNIT 26: BIOMOLECULES 
General introduction and importance of biomolecules. CARBOHYDRATES – Classification: aldoses and ketoses; monosaccharides (glucose and fructose) and constituent monosaccharides of oligosacchorides (sucrose, lactose and maltose). PROTEINS – Elementary Idea of r – amino acids, peptide bond, polypeptides; Proteins: primary, secondary, tertiary and quaternary structure (qualitative idea only), denaturation of proteins, enzymes. VITAMINS – Classification and functions. NUCLEIC ACIDS – Chemical constitution of DNA and RNA. Biological functions of nucleic acids. 
UNIT 27: CHEMISTRY IN EVERYDAY LIFE 
Chemicals in medicines – Analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamins – their meaning and common examples. 
Chemicals in food – Preservatives, artificial sweetening agents – common examples. Cleansing agents – Soaps and detergents, cleansing action. 

UNIT 28: PRINCIPLES RELATED TO PRACTICAL CHEMISTRY 
Detection of extra elements (N,S, halogens) in organic compounds; Detection of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl and amino groups in organic compounds. 
Chemistry involved in the preparation of the following: Inorganic compounds: Mohr’s salt, potash alum. Organic compounds: Acetanilide, pnitroacetanilide, aniline yellow, iodoform. 

Chemistry involved in the titrimetric excercises – Acids bases and the use of indicators, oxalicacid vs KMnO4, Mohr’s salt vs KMnO4. 

Chemical principles involved in the qualitative salt analysis: Cations – Pb2+ , Cu2+, AI3+, Fe3+, Zn2+, Ni2+, Ca2+, Ba2+, Mg2+, NH4+. Anions CO3 2, S2, SO4 2, NO2, NO3, CI , Br, I. (Insoluble salts excluded). 

Chemical principles involved in the following experiments: 
Enthalpy of solution of CuSO4 
Enthalpy of neutralization of strong acid and strong base. 

Preparation of lyophilic and lyophobic sols. 

Kinetic study of reaction of iodide ion with hydrogen peroxide at room temperature. 