Concept:A haloalkyne is an alkyne in which a halogen atom is directly attached to an
sp-hybridised carbon of the triple bond.
Explanation:In chloroethyne, the structure is
H−C≡C−Cl.
Here, the chlorine atom is directly bonded to an
sp-hybridised carbon atom, so chloroethyne is correctly classified as a haloalkyne.
In the remaining options, chlorine is attached to an
sp3-hybridised carbon that is adjacent to the triple bond.
Such compounds are propargylic halides, not haloalkynes.
Hence, only option A fits the definition.
Answer:Option A – Chloroethyne.