Concept:The oxidation number of an element in a polyatomic ion is calculated by equating the sum of all oxidation states to the overall ionic charge.
Explanation:Let the oxidation number of Mn be
x.
In
MnO4−, oxygen has an oxidation number of
−2.
There are 4 oxygen atoms, so their total contribution is
4×(−2)=−8.
The sum of all oxidation numbers must equal the charge on the ion, which is
−1.
Thus, the equation becomes
x+(−8)=−1.
Simplifying,
x−8=−1.
Adding 8 to both sides gives
x=+7.
Hence, manganese in the permanganate ion has an oxidation number of
+7.
Answer:The oxidation number of Mn in
MnO4− is
+7.
Correct option: D. 7