Concept:Covalent crystals are network solids in which atoms are linked by strong covalent bonds in a continuous three-dimensional structure.Explanation:SiO2 is a covalent crystal because each silicon atom is covalently bonded to oxygen atoms, forming a three-dimensional network.Fe is a metallic solid, held together by metallic bonding.CH4 is a molecular solid, with molecules held by weak intermolecular forces.KCl is an ionic solid, consisting of K+ and Cl− ions.Thus, only SiO2 behaves as a covalent crystal.Answer:Option C: SiO2