Concept:In coordination compounds, ligands can be neutral, positively charged, or negatively charged.
Explanation:Ammonia is
NH3​, which is a neutral ligand.
Methylamine is
CH3​NH2​, which is also a neutral ligand.
Hydrazinium is
N2​H5+​, which carries a positive charge.
Nitrate is
NO3−​, which carries a negative charge.
Therefore, among the given options, the negative ligand is nitrate.
Answer:Option D: Nitrate
(NO3−​)