We are given the following information:
- Normality (N) = 0.02 N
- Volume of solution = 50 mL = 0.050 L
- Molar mass of oxalic acid = 126 g/mol
We know that normality
N is related to molarity
M by the equation:
N=n×Mwhere
n is the number of equivalents per mole. For oxalic acid (H
2​C
2​O
4​), the number of replaceable hydrogen ions
n is 2, because each molecule of oxalic acid can donate two protons (H
+) in a reaction.
Therefore, the molarity of the oxalic acid solution is:
M=nN​=20.02​=0.01mol/LNow, the amount of substance (in moles) present in 50 mL (0.050 L) of the solution is:
molesofoxalicacid=M×Volume=0.01×0.050=0.0005molFinally, to find the mass, we use the molar mass of oxalic acid:
mass=moles×molarmass=0.0005×126=0.063g=63mgThus, the mass of oxalic acid in 50 mL of the solution is
63mg​. Quick Tip: In solutions, normality (N) is used to express the equivalent concentration of a solution. Remember, normality is related to molarity by the number of replaceable ions or equivalents in the solution.