Since, we know that,
λ1=Rz2(n121−n221)......(i)
where,
λ= wavelength of light emitted.
R= Rydberg's constant,
Z= atomic number,
n1= principal quantum number of lower energy level
and
n2= principal quantum number of higher energy level.
Therefore, for
1st spectral line of Balmer series,
n1=2 and
n2=3 λ11=Rz2(221−321) ⇒λ11=Rz2(365)...(ii)
Similarly, for 3rd spectral line,
n1=2 and
n2=5 λ31=Rz2(221−521) ⇒λ31=Rz2(10021)......(iii)
Now, dividing Eq. (iii) by Eq. (ii), we get
λ11λ31=Rz2(365)Rz2(10021)⇒λ3λ1=10021×536 ⇒λ3λ1=1.512=15.12×10−1 Comparing with the given value in the question i.e.,
x×10−1, the value of
x=15.