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Test Index
Coordination Compounds Part 1
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Section:
Chemistry
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Question : 19 of 100
Marks:
+1
,
-0
Among the statements(a)-(d), the incorrect ones are-
(a) Octahedral Co(III) complexes with strong field ligands have very high magnetic moments
(b) When
Δ
0
<
P
\Delta_0 < P
Δ
0
<
P
, the d-electron configuration of Co(III) in an octahedral complex is
t
e
g
4
e
g
2
t_{eg}^4 e_g^2
t
e
g
4
e
g
2
(c) Wavelength o f light absorbed by
[
C
o
(
e
n
)
3
]
3
+
[\mathrm{Co}(\mathrm{en})_3]^{3+}
[
Co
(
en
)
3
]
3
+
is lower than that of
[
C
o
F
6
]
3
−
[\mathrm{CoF}_6]^{3-}
[
CoF
6
]
3
−
(d) If the
Δ
0
\Delta_0
Δ
0
for an octahedral complex of Co(III) is 18,000 cm
−
1
^{-1}
−
1
, the At for its tetrahedral complex with the same ligand will be 16,000
cm
−
1
\text{cm}^{-1}
cm
−
1
[7 Jan 2020 Shift 2]
(a) and (b) only
(c) and (d) only
(b) and (c) only
(a) and (d) only
Validate
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