Statement I is correct.The first ionization enthalpies are
B=801Â kJ/mol,
Al=577Â kJ/mol and
Ga=579Â kJ/mol.
The decrease from
B to
Al is
801−577=224 kJ/mol.
The change from
Al to
Ga is
577 to
579Â kJ/mol, i.e. no significant decrease (a small increase of
2Â kJ/mol).
Thus, the decrease from
B to
Al is much larger than that from
Al to
Ga.
Statement II is correct.The electronic configuration of
Ga is
[Ar]3d104s24p1.
Its
3d orbitals are completely filled.
Therefore, statement II is true.
Hence, both Statement I and Statement II are correct.
The correct option is: Both the statements I and II are correct.