Concept:Find the longest carbon chain that includes the ketone group, then number it so the ketone carbon gets the lowest possible number.
Explanation:Mesityl oxide has the structure
(CH3​)2​C=CH−CO−CH3​.
The longest chain containing the
C=O group has
5 carbon atoms, so the parent is pentane.
Numbering starts from the ketone end, so the
C=O is at position
2.
Thus the base name becomes pent-
2-one.
A double bond lies at position
3, giving pent-
3-en-
2-one.
A methyl group is attached at position
4.
Combining all parts gives
4-methylpent-
3-en-
2-one.
Answer:The
IUPAC name of mesityl oxide is
4-methylpent-
3-en-
2-one.