(A)
Pb>50 ppm→ Lead toxicity causes liver and kidney damage, neurological disorders, etc.
So, (A) → (IV) Liver damage
(B)
SO42−>500 ppm→ High sulfate content in water has a laxative effect.
So, (B) → (III) Laxative effect
(C)
NO3−>50 ppm→ High nitrate levels cause methemoglobinemia ('Blue baby' syndrome) in infants.
So, (C) → (II) 'Blue baby' syndrome
(D)
F−>2ppm
→ Excess fluoride causes fluorosis → brown mottling of teeth.
So, (D) → (I) Brown mottling of teeth
Correct matching:
A-IV, B-III, C-II, D-I