When sulphur ( S ) is heated with Na2SO3, a compound Na2S2O3(A) is produced. When Na2S2O3 react with excess of AgNO, solution, it will give a Ag2S2O3(B) whichis a water soluble compound. Further Ag2S2O3 dissolves in water, to produce a black coloured sulphide Ag2S(C).
S
Sulphur
+
Na2SO3
Sodium
sulphate
→
Na2S2O3
(A)
Sodium‌thiosulphate
Na2S2O3
Sodium
thiosulphate
+2
AgNO3
Excess
→
Ag2S2O3
(B)
Silver‌thiosulphate
+2NaNO3
Ag2S2O3
Silver
thiosulphate
+H2O→
Ag2S(C)
(Black)
Silver‌sulphide
+H2SO4 Hence, compound A is Na2S2O3,B is Ag2S2O3 and C is Ag2S.