For O2+ Molecular orbital configuration of O2+ is σ1s2σ*1s2σ2s2σ*2s2σ2pz2π2px2≈π2py2π*2px1 Number of electrons in bonding orbital =10 Number of electrons in antibonding orbital =5 Bond order of NO2+=
10−5
2
=2.5 For NO+ Molecular orbital configuration is σ1s2σ*1s2σ2s2σ*2s2π2px2π2py2σ2pz2 Number of electrons in bonding orbital =10 Number of electrons in antibonding orbital =4 Bond order =