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NCERT Class XI Chemistry Some Basic Concepts of Chemistry Solutions

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Question : 6 of 36
Marks: +1, -0
Calculate the concentration of nitric acid in moles per litre in a sample which has a density, 1.41 g mL−1\mathrm{g}\,\mathrm{mL}^{-1} and the mass per cent of nitric acid in it being 69%.
Solution:  
69 mass per cent of nitric acid means that 69 g of HNO3\mathrm{HNO}_3 is present in 100 g of solution.
∴ Volume of solution = MassDensity\frac{\text{Mass}}{\text{Density}} = 100 g1.41 g mL−1\frac{100\,\mathrm{g}}{1.41\,\mathrm{g}\,\mathrm{mL}^{-1}} = 70.92 mL
Moles of HNO3\mathrm{HNO}_3 = 6963\frac{69}{63} = 1.095
Molarity = Moles of HNO3Volume of soln. in mL\frac{\text{Moles of }\mathrm{HNO}_3}{\text{Volume of soln. in }\mathrm{mL}} × 1000 = 1.09570.92\frac{1.095}{70.92} × 1000 = 15.44 M
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