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NCERT Class XI Chemistry Hydrogen Solutions

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Question : 9 of 36
Marks: +1, -0
What characteristics do you expect from an electron-deficient hydride with respect to its structure and chemical reactions?
Solution:  
It is expected to be a Lewis acid. For example, diborane B2H6B_2H_6 (dimer of BH3BH_3) forms complex with LiH which gives H– ion (Lewis base).
2LiHLithiumhydride(Lewisbase)\underset{Lithium hydride (Lewis base)}{2LiH} + B2H6Diborane(Lewisacid)\underset{Diborane (Lewis acid)}{B_2H_6} → 2Li+[BH4]−Lithium borohydride (Complex)\underset{\text{Lithium borohydride (Complex)}}{\mathrm{2Li^{+}[BH_4]^{-}}}
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