NCERT Class XII Chemistry
Chapter - The p-Block Elements
Questions with Solutions

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Question : 31
Total: 74
What are the oxidation states of phosphorus in the following :
(i) H3PO3
(ii) PCl3
(iii) Ca3P2
(iv) Na3PO4
(v) POF3?
Solution:  
Let the oxidation state of P be x.
(i)
+1‌‌x−2
H3PO3
∴3(+1)+x+3(–2)=0 or x=+3


(ii)
x −1
PCl3
∴x+3(–1)=0 or x=+3


(iii)
+2‌‌‌x
Ca3P2
∴3(+2)+2×x=0
or x=−3

(iv)
+1‌‌‌x−2
Na3PO4
∴3(+1)+x+4(−2)=0
or x=+5

(v)
x−2‌−1
P O F3
∴x+1(−2)+3(−1)=0
or x=+5
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