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NCERT Class XI Chemistry Solutions

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Question : 25 of 40
Marks: +1, -0
Describe the change in hybridisation (if any) of the Al atom in the following reaction.
AlCl3+ClAlCl_3 + Cl^{–}AlCl4AlCl_4^{–}
Solution:  
There is change in hybridization from sp2sp^2sp3sp^3. In AlCl3AlCl_3, Al is sp2sp^2 hybridised. AlCl3AlCl_3 thus has three sp2sp^2 hybrid orbitals and a vacant unhybrid p-orbital. When AlCl4AlCl_4^{–} is formed, Al undergoes sp3sp^3 hybridisation and thus ClCl^{–} overlaps with the fourth orbital.
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