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NCERT Class XI Chemistry Redox Reactions Solutions
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Question : 20 of 30
Marks:
+1,
-0
What sorts of informations can you draw from the following reaction? →
Solution:
Let x be the oxidation number of C. ∴ O.N. of C in cyanogen, = 2(x – 3) = 0 or x = +3 O.N. of C in cyanide ion, = x – 3 = –1 or x = +2 O.N. of C in cyanate ion, = x – 3 – 2 = –1 or x = +4 The four informations about the reaction are : (i) The reaction involves decomposition of cyanogen, in the alkaline medium to cyanide ion, and cyanate ion, . (ii) The O.N. of C decreases from +3 in to + 2 in ion and increases from +3 in to +4 in ion. Thus, cyanogen is simultaneously reduced to cyanide ion and oxidised to cyanate ion. (iii) It is an example of disproportionation redox reaction. (iv) Cyanogen is a pseudohalogen while cyanide ion is a pseudohalide ion.
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