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NCERT Class XI Chemistry Redox Reactions Solutions

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Question : 16 of 30
Marks: +1, -0
Why does the following reaction occur ?
XeO64(aq)+2F(aq)+6H+(aq)\mathrm{XeO_6^{4-}(aq)} + 2\mathrm{F^{-}(aq)} + 6\mathrm{H^{+}(aq)}XeO3(g)+F2(g)+3H2O(l)\mathrm{XeO_{3(g)}} + \mathrm{F_{2(g)}} + 3\mathrm{H_2O_{(l)}}
What conclusion about the compound Na4XeO6\mathrm{Na_4XeO_6} (of which XeO64\mathrm{XeO_6^{4-}} is a part) can be drawn from the reaction?
Solution:  
IXeO64(aq)+2F(aq)+6H(aq)+\mathrm{XeO_6^{4-}{}_{(aq)}} + 2\mathrm{F^{-}_{(aq)}} + 6\mathrm{H^{+}_{(aq)}}XeO3(g)+F2(g)+3H2O(l)\mathrm{XeO_{3(g)}} + \mathrm{F_{2(g)}} + 3\mathrm{H_2O_{(l)}}
n this reaction, O.N. of Xe decreases from +8 in XeO64\mathrm{XeO_6^{4-}} to +6 in XeO3\mathrm{XeO_3} while that of F increases from –1 in F\mathrm{F^{-}} to 0 in F2\mathrm{F_2}. Therefore, XeO64\mathrm{XeO_6^{4-}} is reduced while F\mathrm{F^{-}} is oxidised. From this reaction it is concluded that Na4XeO6\mathrm{Na_4XeO_6} is a stronger oxidising agent than F2\mathrm{F_2}.
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