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NCERT Class XI Chemistry Hydrogen Solutions

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Question : 36 of 36
Marks: +1, -0
What do you understand by the terms :
(i) hydrogen economy
(ii) hydrogenation
(iii) syngas
(iv) water-gas shift reaction
(v) fuel-cell ?
Solution:  
(i) Hydrogen economy : The energy is transported and stored in the form of liquid or gaseous hydrogen is the principle due to which hydrogen is considered to be a possible source of clean energy. This proposal to use hydrogen as fuel is called hydrogen economy.
(ii) Hydrogenation : The process of addition of hydrogen to unsaturatedhydrocarbons is known as hydrogenation.
H2C=CH2Ethene+H2\underset{\text{Ethene}}{\mathrm{H}_2\mathrm{C}=\mathrm{CH}_2}+\mathrm{H}_2 →473 KNi or Pt or Pd\xrightarrow[473\,\text{K}]{\text{Ni or Pt or Pd}} H3C−CH3Ethane\underset{\text{Ethane}}{\mathrm{H}_3\mathrm{C}-\mathrm{CH}_3}
H−C≡C−HEthyne+2H2\underset{\text{Ethyne}}{\mathrm{H}-\mathrm{C}\equiv \mathrm{C}-\mathrm{H}}+2\mathrm{H}_2 →473 KNi or Pt or Pd\xrightarrow[473\,\text{K}]{\text{Ni or Pt or Pd}} H3C−CH3Ethane\underset{\text{Ethane}}{\mathrm{H}_3\mathrm{C}-\mathrm{CH}_3}
(iii) Syngas : The mixture of CO and H2 is used for the synthesis of methanol and a number of hydrocarbons, it is also called synthesis gas or syngas. Nowadays, syngas is produced from sewage, saw dust, scrap wood, newspapers, etc.
(iv) Water-gas shift reaction : The production of dihydrogen can be increased by reacting CO of syngas mixtures with steam in the presence of iron chromate as catalyst.
CO(g)+H2O(g)\mathrm{CO}_{(g)}+\mathrm{H}_2\mathrm{O}_{(g)} →Catalyst673 K\xrightarrow[\text{Catalyst}]{673\,\text{K}} CO2(g)+H2(g)\mathrm{CO}_{2(g)}+\mathrm{H}_{2(g)}
This is called water-gas shift reaction.
(v) Fuel cell : It is a commercial cell in which the chemical energy produced during the combustion of fuel is converted directly into electricity, e.g., H2 – O2\mathrm{H}_2\ \text{--}\ \mathrm{O}_2 fuel cell. A fuel cell is used as a source of electrical energy in the space vehicles.
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