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NCERT Class XI Chemistry Hydrogen Solutions

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Question : 23 of 36
Marks: +1, -0
Discuss the principle and method of softening of hard water by synthetic ion-exchange resins.
Solution:  
Hard water is made soft by a very common ion exchange resin method. In this the hard water is allowed to pass over a zeolite bed [zeolites are sodium aluminium silicates (Na2Al2Si2O8â‹…xH2O)](\mathrm{Na}_2\mathrm{Al}_2\mathrm{Si}_2\mathrm{O}_8\cdot x\mathrm{H}_2\mathrm{O})] during which the Na+ ions from zeolite are replaced by Ca2+ and Mg2+ ions.
Na2Z+Ca2+→CaZ+2Na+\mathrm{Na}_2\mathrm{Z} + \mathrm{Ca}^{2+} \rightarrow \mathrm{CaZ} + 2\mathrm{Na}^{+}
Na2Z+Mg2+→MgZ+2Na+\mathrm{Na}_2\mathrm{Z} + \mathrm{Mg}^{2+} \rightarrow \mathrm{MgZ} + 2\mathrm{Na}^{+}
When whole of the Na+\mathrm{Na}^{+} ions of the zeolite have been exchanged, the zeolite is regenerated by treating it with strong (or saturated) solution of NaCl.
MZ + 2NaCl → Na2Z+MCl2\mathrm{Na}_2\mathrm{Z} + \mathrm{MCl}_2 (M = Mg, Ca)
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