NCERT Class XI Chemistry Hydrocarbons Solutions

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Question : 3
Total: 25
For the following compounds, write structural formulae and IUPAC names of all possible isomers having the number of double or triple bond as indicated :
(a) C4H8 (one double bond)
(b) C5H8 (one triple bond)
Solution:  
(a) C4H8 can have the following structures with one single double bond :
(i) But - 1 - ene
H3C−H2C−HC=CH2
(ii) 2 - Methylprop - 1 - ene
H3C−
C
|
CH3
=CH2

(iii) But - 2 - ene
H3C−HC=CH−CH3

(b) C5H8 can have the following structures with one triple bond :
(i) Pent - 1 - yne
H3C−H2C−H2C−C≡CH
(ii) Pent - 2 - yne
H3C−H2C−C≡C−CH3
(iii) 3 - Methylbut - 1 - yne
H3C−
H
|
CH3
C
−C
≡CH
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