CBSE Class 12 Chemistry 2020 Delhi Set 1 Solved Paper

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Question : 32
Total: 37
Give the structures of final products expected from the following reactions :
(i) Hydroboration of propene followed by oxidation with H2O2 in alkaline medium.
(ii) Dehydration of (CH3)3C−OH by heating it with 20%H3PO4 at 358K.

OR
How can you convert the following?
(i) Phenol to o-hydroxybenzaldehyde
(ii) Methanal to ethanol
(iii) Phenol to phenyl ethanoate
Solution:  
(i)

(ii)
CH3−
CH3
|
C
|
CH3
−OH
t−butyl‌alcohol(2‌methyl−2−propanol)
20%H3PO4
────▸
358K
CH3−
C
|
CH3
=CH2+H2O
2‌methylpropene(Isobutylene)

(iii) C6H5‌OH+
(CH3‌CO)2O
Acetic‌anhydride
→
CH3COOC6H5
Phenylethanoate
+CH3‌COOH

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