CBSE Class 12 Chemistry 2016 Delhi Set 1 Solved Paper

© examsnet.com
Question : 7
Total: 26
When chromite ore FeCr2O4 is fused with NaOH in presence of air, a yellow coloured compound
(A) is obtained which on acidification with dilute sulphuric acid gives a compound (B). Compound
(B) on reaction with KCl forms a orange coloured crystalline compound (C).
(i) Write the formulae of the compounds (A), (B) and (C).
(ii) Write one use of compound (C).
OR
Complete the following chemical equations:
(i) MnO4−+3S2O32−+H2O→ ?
(ii) Cr2O72−+3Sn2++14H+→ ?
Solution:  
(i) ‌4FeCr2O4+16‌NaOH+7O2→ 8Na2CrO4[A]+‌2Fe2O3+8H2O
‌Na2Cr2O7[B]+2‌KCl→K2Cr2O7[C]+2‌NaCl
‌A:Na2CrO4B:Na2Cr2O7C:K2Cr2O7
(ii) Use of K2Cr2O7(C) : It is used as a strong oxidizing agent in industries.
OR
(i) 8MnO4−+3S2O32−+H2O→8MnO2 +6SO42−+2OH−
(ii) Cr2O72−+3Sn2++14H+→2Cr3+ +7H2O+3Sn4+
© examsnet.com
Go to Question: